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1989-3-7 & 0183; According to the invention a clay such as a hydrous kaolin clay i.e. a kaolin that has not been subjected to calcination can be coated with a silicon nitride layer when reacted at above 1000& 176; C. preferably 1100& 176; to 1500& 176; C. in a gaseous NH 3 atmosphere. The novel product is gray in color will not disperse in organic or inorganic
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Silicon nitride undergoes hydrolysis and dissolution when subjected to an aqueous environment. Molecular dynamics simulations suggest that hydrolysis proceeds through nucleophilic attack of water with the formation of an intermediate molecular complex involving a pentacoordinated silicon.